4,4′,4′′-Tris(2-pyridyl)-2,2′,2′′-[(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tris(sulfanediyl)]tripyrimidine
نویسندگان
چکیده
The title compound, C(39)H(33)N(9)S(3), features a mesitylene unit substituted with three thio-ether arms. The distances from the center of mesitylene unit to the N atoms of the three pyridine rings in the arms are 10.05 (1), 9.94 (3) and 8.79 (3) Å. The crystal structure shows weak intra-molecular C-H⋯N hydrogen bonds.
منابع مشابه
2,2′,2′′-[(2,4,6-Trimethoxybenzene-1,3,5-triyl)tris(methylene)]tris(isoindole-1,3-dione)
The title mol-ecule, C36H27N3O9, adopts an almost symmetric conformation in which the mean planes of the phthalimido units are inclined at dihedral angles of 81.1 (1), 85.3 (1) and 86.3 (1)° with respect to the plane of the central aromatic ring. The O atoms are involved in intra- and inter-molecular C-H⋯O hydrogen bonding. The crystal structure also features π-π arene inter-actions [minimum ri...
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In the title compound, [Nd(NO(3))(3)(C(18)H(12)N(6))(H(2)O)]·2H(2)O, the Nd(3+) ion is in a distorted bicapped square-anti-prismatic geometry formed by three N atoms from the 2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine (TPTZ) ligand, six O atoms from the three nitrate anions and one O atom from the aqua ligand. The mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds. Two types of π-π stacking ...
متن کامل5,5′,5′′-Triphenyl-2,2′,2′′-[2,4,6-trimethylbenzene-1,3,5-triyltris(methylidenesulfanediyl)]tris(1,3,4-oxadiazole)
In the title compound, C(36)H(30)N(6)O(3)S(3), the phenyl rings are twisted from the attached oxadiazole rings in the three arms by 1.5(2), 2.4 (2) and 25.7 (2)°. The crystal packing exhibits weak inter-molecular C-H⋯N inter-actions.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009